Journal
GREEN CHEMISTRY
Volume 17, Issue 7, Pages 3756-3761Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c5gc00759c
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A cross-metathesis procedure was developed to synthetize symmetrical and non symmetrical stilbenes from sustainable resources. The reaction proceeds under solvent-free conditions and at low catalyst loading (down to 0.01 mol%) within a couple of minutes only (TOF up to 6.9 s(-1)), on multi-gram scale. The highly reactive beta-methylstyrene substrates were homo-coupled not only as pure synthons but also as components of essential oils that were reacted directly in order to eliminate prior substrate isolation from the overall process.
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