Journal
GREEN CHEMISTRY
Volume 17, Issue 7, Pages 3910-3915Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c5gc00871a
Keywords
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Funding
- Natural Science Foundation of China [21273239, 21471151]
- Natural Science Foundation of Fujian Province [2011J01064]
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A thorough study of environmentally friendly hydroxylation of aryl halides is presented. The best protocol consists of hydroxylation of different aryl bromides and electron-deficient aryl chlorides by water solution of tetrabutylammonium hydroxide catalyzed by Cu2O/4,7-dihydroxy-1,10-phenanthroline. Various phenol derivatives can be obtained in excellent selectivity and great functional group tolerance. This methodology also provides a direct pathway for the formation of alkyl aryl ethers and benzofuran derivatives in a one-pot tandem reaction.
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