4.8 Article

B(C6F5)(3)-catalyzed methylation of amines using CO2 as a C1 building block

Journal

GREEN CHEMISTRY
Volume 17, Issue 8, Pages 4189-4193

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/c5gc01386k

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Funding

  1. National Natural Science Foundation of China [21125314, 21321063, 21402208]

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B(C6F5)(3) was proven to be an efficient metal-free catalyst for the methylation of amines using CO2 as a C1 building block in the presence of hydrosilanes under easy-handling conditions. A broad range of N-alkylanilines, dialkylamines and primary anilines all proceeded well under the catalytic conditions.

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