4.8 Article

Double carbonylation of aryl iodides with amines under an atmospheric pressure of carbon monoxide using sulfur-modified Au-supported palladium

Journal

GREEN CHEMISTRY
Volume 17, Issue 4, Pages 2358-2361

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/c4gc02469a

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Funding

  1. JSPS [26460002, 26293001]
  2. MEXT, Japan [23105501, 25105701]
  3. Grants-in-Aid for Scientific Research [25670049, 25105701, 15H02495, 26288051, 23246013, 25105702, 26293001, 26460002] Funding Source: KAKEN

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A double carbonylation of aryl iodides with amines proceeded smoothly under an atmospheric pressure of carbon monoxide by using palladium nanoparticles (Pd NPs) leached from a sulfur-modified Au-supported palladium material (SAPd), producing alpha-ketoamides in good to excellent yields.

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