4.8 Article

Noyori-Ikariya catalyst supported on tetra-arylphosphonium salt for asymmetric transfer hydrogenation in water

Journal

GREEN CHEMISTRY
Volume 17, Issue 6, Pages 3255-3259

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/c5gc00086f

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Funding

  1. Fonds Quebecois de la Recherche sur la Nature et les Technologies (FQRNT)
  2. Canada Foundation for Innovation
  3. Canada Research Chair Program
  4. FRQNT Centre in Green Chemistry and Catalysis (CGCC)
  5. Universite de Montreal
  6. Swiss National Science Foundation

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A straightforward synthesis of a tetraarylphosphonium (TAP)-supported Noyori-Ikariya catalyst is described. The TAP-supported ruthenium precatalyst provided good conversions and high enantioselectivities for the asymmetric transfer hydrogenation of ketones in water. In addition the catalyst was easily recovered and used in multiple catalytic cycles.

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