Journal
GREEN CHEMISTRY
Volume 17, Issue 8, Pages 4281-4290Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c5gc00810g
Keywords
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Funding
- National Natural Science Foundation of China [21133011, 21203221, 21473224]
- Natural Science Foundation of Gansu province [1308RJZA281]
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Copper-silica nanocomposite catalysts with a uniform Cu dispersion prepared by a precipitation-gel method have been found to be highly efficient in the heterogeneous catalytic hydrogenation of CO2-derived cyclic carbonates, providing an indirect but practical approach for the transformation of CO2 to methanol with the co-production of diols under relatively mild conditions. The catalysts possessed remarkable stability in both batch and fixed-bed continuous flow reactors especially after promotion with B2O3. The reaction was found to depend sensitively on the Cu particle size, the surface acidity-basicity and the Cu valence of the catalysts. The synergetic effect between balanced Cu-0 and Cu+ sites was considered to play a critical role in attaining high yields of methanol and diols.
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