4.8 Article

Facile route to conformal hydrotalcite coatings over complex architectures: a hierarchically ordered nanoporous base catalyst for FAME production

Journal

GREEN CHEMISTRY
Volume 17, Issue 4, Pages 2398-2405

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/c4gc01689k

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Funding

  1. EPSRC [EP/G007594/4]
  2. Leadership Fellowship and studentship
  3. Royal Society for the award of an Industry Fellowship
  4. EPSRC [EP/K000616/2, EP/K000616/1, EP/G007594/4] Funding Source: UKRI
  5. Engineering and Physical Sciences Research Council [EP/K000616/1, EP/G007594/4, EP/K000616/2] Funding Source: researchfish

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An alkali- and nitrate-free hydrotalcite coating has been grafted onto the surface of a hierarchically ordered macroporous-mesoporous SBA-15 template via stepwise growth of conformal alumina adlayers and their subsequent reaction with magnesium methoxide. The resulting low dimensional hydrotalcite crystallites exhibit excellent per site activity for the base catalysed transesterification of glyceryl triolein with methanol for FAME production.

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