Journal
JOURNAL OF NATURAL PRODUCTS
Volume 81, Issue 4, Pages 1121-1124Publisher
AMER CHEMICAL SOC
DOI: 10.1021/acs.jnatprod.8b00164
Keywords
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Funding
- National Natural Science Foundation of China [31670355]
- Natural Science Foundation for Distinguished Young Scholars of Shandong Province [JQ201712]
- Open Fund of Key Laboratory of Experimental Marine Biology, CAS [KF2017NO4]
- Youth Innovation Promotion Association of CAS [201780]
- Yantai Institute of Coastal Zone Research, CAS [Y755031012]
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Three novel polyketide-like metabolites, trichorenins A-C (1-3), with a unique tetracyclic carbon skeleton were obtained from the culture of Trichoderma virens Y13-3, an epiphyte of the marine red alga Gracilaria vermiculophylla. Their structures and relative configurations were established by analysis of 1D/2D NMR and MS data, and their absolute configurations were unequivocally assigned by X-ray diffraction and ECD spectra aided by quantum chemical calculations. Compounds 1-3 exhibited potent inhibition against two marine phytoplankton species, Chattonella marina and Karlodinium veneficum.
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