Journal
JOURNAL OF NANOSCIENCE AND NANOTECHNOLOGY
Volume 18, Issue 2, Pages 1103-1109Publisher
AMER SCIENTIFIC PUBLISHERS
DOI: 10.1166/jnn.2018.13969
Keywords
PVA; Conductance; Impedance; Polymer; XRD; FTIR
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Polymer blend electrolytes based on magnesium ion conducting PVA-PVP-MgCl2 polymer were prepared at different compositions by solution casting techniques. The prepared films were characterised by various techniques such as XRD and FTIR. Amorphous nature and structural coordination of polymer electrolyte were confirmed by X-ray diffraction and Fourier transform infrared spectroscopy studies. The ionic conductivity of the prepared polymer electrolytes were analysed through ac impedance spectroscopy. The highest conductivity was found to be in the order of similar to 10(-6) Scm(-1) at an ambient temperature for the composition of 50PVA:50PVP: 5 wt% MgCl2. Conductivity versus temperature plot was found to follow an Arrhenius nature. The dielectric behaviour and ionic transport properties of the polymer electrolytes were also analyzed.
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