Journal
JOURNAL OF MOLECULAR STRUCTURE
Volume 1159, Issue -, Pages 205-215Publisher
ELSEVIER SCIENCE BV
DOI: 10.1016/j.molstruc.2018.01.062
Keywords
1-Benzl-3-Methylimidazolium chloride; 1-Hexyl-3-methylimidazolium chloride; Inclusion complex; Alpha cyclodextrin; Beta cyclodextrin
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Funding
- University Grants Commission, New Delhi, India [540/27/DRS/2007]
- UGC-RGNF India [F117.1/201617/RGNF201517SCWES1846, F.1/2012-13/RGNF2012-13-SC-WES-17229]
- UGC, New Delhi, Govt. Of India under the Basic Scientific Research [F4-10/2010 (BSR)]
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The formation of the host-guest inclusion complexes of ionic liquids namely [BMIm]CI and [HMIm]CI with alpha-CD and beta-CD were studied by means of physicochemical and spectroscopic methods. Conductivity and surface tension study were in good agreement with the 1H NMR and FT-IR studies which confirm the formation of the inclusion complexes. The Density and viscosity study also supported the formation of the ICs. Further the stoichiometry was determined 1:1 for each case and the association constants and thermodynamic parameters derived supported the most feasible formation of the [BMIm]Cl- beta-CD inclusion complex. (C) 2018 Elsevier B.V. All rights reserved.
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