4.7 Article

Thermal stability of choline based amino acid ionic liquids

Journal

JOURNAL OF MOLECULAR LIQUIDS
Volume 266, Issue -, Pages 597-602

Publisher

ELSEVIER
DOI: 10.1016/j.molliq.2018.06.096

Keywords

Amino acids; Ionic liquids; Choline; Thermal stability

Funding

  1. Norrbotten Research Council (NoFo) [17-103]
  2. Kempe foundation [JCK-1707]

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Thermal stability of different choline based amino acid ionic liquids were studied. Both short term as well as long term thermal studies were carried out. Long term thermal studies of all ILs were carried out by isothermal TGA and short term thermal studies were measured by temperature ramped TGA. Isothermal TGA were studied at two different temperatures 100 degrees C and 150 degrees C for 500 min. Whereas, short term thermal stability represents as T-2%, T-5% and T-10% which are the temperature at which 2%, 5% and 10% mass loss of ILs were observed. The effect of alkyl side chain on the cation, etherification of the cation as well structural variation of anion on the thermal stability of choline based ILs were investigated. It was observed that thermal characteristics of ILs towards temperature ramped TGA were different compared to isothermal TGA. (C) 2018 Elsevier B.V. All rights reserved.

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