4.6 Article

Effect of Hot Rolled Substrate of Hydrogen Reduction on Interfacial Reaction Layer of Hot-dip Galvanizing

Journal

JOURNAL OF MATERIALS PROCESSING TECHNOLOGY
Volume 259, Issue -, Pages 134-140

Publisher

ELSEVIER SCIENCE SA
DOI: 10.1016/j.jmatprotec.2018.04.027

Keywords

Porous and dense surface; Galvanizing; Inhibition layer; Hydrogen reduction

Funding

  1. National Natural Science Foundation of China [51674163, 51104098]
  2. Science and Technology Committee of Shanghai [16ZR1412000, 14521100603]
  3. Analysis and Test Center of Shanghai University

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The effect of morphology of substrate on intermetallic layer is studied in this work by combining the hydrogen reduction descaling of hot rolled steel and galvanizing process. The results show that the morphology of iron reduced at different temperatures can be divided into porous and dense iron surface. The interfacial reaction layer on steel strip with porous iron is composed of xi phase and delta phase, and the phase in coating is invariable with the increasing of soaking time. However, the interfacial reaction layer on steel strip with dense iron is considered to be Fe2Al5Znx intermetallic layer. As the time goes up, a columnar xi phase forms on the intermetallic layer of steel strip reduced at 700 degrees C and the Fe-Al intermetallic layer disappears gradually. In addition, the bursting phenomenon of intermetallic layer occurs after dipping for 10s on steel strip reduced at 800 degrees C, and the delta phase forms on the interface between the outburst Fe-Al phase and substrate. The possible mechanisms involved in the formation of Fe-Al and Fe-Zn alloys were also discussed.

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