Luminescence and electronic structure of Nd3+ complex with pyrazole-substituted 1,3-diketone and 1,10-phenanthroline

We studied luminescent properties of two Nd3+ complexes with two different ligands. The first one was 1,3-diketone bearing a pyrazole fragment and the second ligand was either 1,10-phenanthroline or RIM. For the ligand environment composed of 1,3-diketone and 1,10-phenanthroline the position of the hybrid triplet level was as low as 18200 cm(-1). The spectral features specific to Nd3+ emission observed in the photoluminescence spectra of the complexes under optical excitation provided the evidence for ion-centered luminescence. Radiative transitions were identified using the obtained spectroscopic data. Corresponding diagram of the energy levels of the complex with 1,10-phenanthroline ligand was developed. Possible energy transfer pathways were discussed.