Journal
JOURNAL OF INDUSTRIAL AND ENGINEERING CHEMISTRY
Volume 66, Issue -, Pages 446-455Publisher
ELSEVIER SCIENCE INC
DOI: 10.1016/j.jiec.2018.06.012
Keywords
Co3O4@Er2O3 nanorods; 4-Hexyl resorcinol; Sensitivity; Glassy carbon electrode; Environmental safety
Funding
- Center of Excellence for Advanced Materials Research, King Abdulaziz University, Jeddah, Saudi Arabia
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In this approach, Co3O4@Er2O3 nanorods (NRs) were prepared by a wet-chemical method using reducing agents in alkaline medium. The resulting nanoparticles were characterized in details by UV/Vis and FT-IR spectroscopy, X-ray powder diffraction, Elemental dispersive analysis (EDS) coupled with field-emission scanning electron microscopy (FESEM). Co3O4@Er(2)O(3)NRs were deposited on a glassy carbon electrode (GCE) to give a selective sensor with a fast response toward 4-hexyl resorcinol (4-HR) in phosphate buffer phase (PBS) by electrochemical approach. The 4-HR sensor also displays good sensitivity, large linear dynamic range, lowest detection limit, and long-term stability, and enhanced electrochemical response. The calibration plot is linear over the 0.1 nM-0.01 M 4-HR concentration range. The sensitivity is similar to 14.765 mu A mu M-1 cm(-2), and the detection limit is 64.29 pM (signal-to-noise ratio, at a SNR of 3). We also discuss possible future prospective uses of this doped metal oxide semiconductor nanomaterial in terms of chemical sensing. (C) 2018 The Korean Society of Industrial and Engineering Chemistry. Published by Elsevier B.V. All rights reserved.
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