Journal
JOURNAL OF INDUSTRIAL AND ENGINEERING CHEMISTRY
Volume 65, Issue -, Pages 13-25Publisher
ELSEVIER SCIENCE INC
DOI: 10.1016/j.jiec.2018.05.009
Keywords
Acetylene hydrochlorination; Non-mercury catalyst; Heterogeneous catalysis; Green process; Industrialization
Funding
- State Key Research and Development Project [2016YFB0301601]
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This review gives a summary on heterogeneous non-mercury catalysts for acetylene hydrochlorination process. First, various catalysts are classified and their performances are compared. Next, studies on catalytic performance by theoretical characterizations and molecule level simulations are introduced. Then, efforts for industrial scaling up and corresponding long-term plant trial results are presented to show enormous potential of state-of-the-art catalysts. Finally, the crucial engineering issues for future industrialization process including kinetic study, reactor design & simulation and material recycling process are proposed. Based on promising achievements, we believe that extensive industrial application of non-mercury catalysts for acetylene hydrochlorination will soon become reality. (C) 2018 The Korean Society of Industrial and Engineering Chemistry. Published by Elsevier B.V. All rights reserved.
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