Journal
JOURNAL OF INDUSTRIAL AND ENGINEERING CHEMISTRY
Volume 65, Issue -, Pages 137-145Publisher
ELSEVIER SCIENCE INC
DOI: 10.1016/j.jiec.2018.04.022
Keywords
Lithium metal battery; Polymer electrolyte; Ionic liquid; Voltammetry; Capacity loss
Funding
- DST, New Delhi, India
- DST-SERB, New Delhi, India
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Flexible gel polymer electrolytes based on polymer polyethylene oxide, salt lithium bis(fluorosulfonyl) imide and ionic liquid 1-ethyl-3-methylimidazolium bis(fluorosulfonyl)imide are synthesized. Prepared samples show high thermal stability, high ionic conductivity at room temperature and an electrochemical stability window of similar to 3.51 V vs. Li/Li+. Lithium deposition-striping voltage profiles show the formation of a stable solid electrolyte interface. A Li/GPE/LiFePO4 cell was assembled by low cost thermal lamination technique. This cell can deliver 143 mAh g(-1) capacity at room temperature at C/20 rate with good discharge efficiency. Use of micro grid mesh type Al current collector in cathode exhibits significant improvement in capacity retention. (C) 2018 The Korean Society of Industrial and Engineering Chemistry. Published by Elsevier B.V. All rights reserved.
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