Journal
GEOPHYSICAL RESEARCH LETTERS
Volume 42, Issue 11, Pages 4402-4410Publisher
AMER GEOPHYSICAL UNION
DOI: 10.1002/2015GL064200
Keywords
hyporheic; microzone; microsite; denitrification; biogeochemical; mass transfer
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Funding
- National Science Foundation [EAR-1446300, EAR-1446328]
- U.S. Geological Survey (USGS) Office of Groundwater, USGS National Research Program
- Groundwater Resources Programand Toxic Substances Hydrology Program
- Leverhulme Trust
- Department of Energy Environmental Remediation Science Program [DE-SC0001773]
- Division Of Earth Sciences
- Directorate For Geosciences [1446328, 1446300] Funding Source: National Science Foundation
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Recent observations reveal a paradox of anaerobic respiration occurring in seemingly oxic-saturated sediments. Here we demonstrate a residence time-based explanation for this paradox. Specifically, we show how microzones favorable to anaerobic respiration processes (e.g., denitrification, metal reduction, and methanogenesis) can develop in the embedded less mobile porosity of bulk-oxic hyporheic zones. Anoxic microzones develop when transport time from the streambed to the pore center exceeds a characteristic uptake time of oxygen. A two-dimensional pore-network model was used to quantify how anoxic microzones develop across a range of hyporheic flow and oxygen uptake conditions. Two types of microzones develop: flow invariant and flow dependent. The former is stable across variable hydrologic conditions, whereas the formation and extent of the latter are sensitive to flow rate and orientation. Therefore, pore-scale residence time heterogeneity, which can now be evaluated in situ, offers a simple explanation for anaerobic signals occurring in oxic pore waters.
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