L-cysteine intercalated layered double hydroxide for highly efficient capture of U(VI) from aqueous solutions

L-cysteine intercalated Mg/Al layered double hydroxide (Cys-LDH) composites were fabricated and applied for treating the U(VI) contaminated wastewater under various conditions. Interaction mechanisms and adsorption properties were investigated by using batch experiments with spectroscopy analysis. The adsorption isotherms and kinetics were fitted perfectly with the Langmuir isotherm and the pseudo-second-order model, respectively. The significant maximum adsorption capacity of Cys-LDH (211.58 mg/g) compared to LDH was attributed to the larger number of functional groups on Cys-LDH. The presence of humic acid (HA) decreased U(VI) elimination on Cys-LDH at high pH but increased U(Vl) removal at low pH. Typically, the presence of various anions (such as Na-3(-), ClO4- and SO42-) did not obviously affect U(VI) adsorption on Cys-LDH, while the coexisted CO32- significantly affected U(VI) elimination. The predominate adsorption were determined to be the formation of Cys-U(Vl)-Cys complexes with cysteine in the Cys-LDH interlayers. The results demonstrated that the Cys-LDH are promising adsorbents for efficient elimination and extraction of radionuclides in actual environmental contamination management. (C) 2018 Elsevier Ltd. All rights reserved.