4.7 Article

The pristine graphene produced by liquid exfoliation of graphite in mixed solvent and its application to determination of dopamine

Journal

JOURNAL OF COLLOID AND INTERFACE SCIENCE
Volume 513, Issue -, Pages 279-286

Publisher

ACADEMIC PRESS INC ELSEVIER SCIENCE
DOI: 10.1016/j.jcis.2017.11.038

Keywords

Graphene; Exfoliation; Mixed solvent; Salt; Electrochemical sensor

Funding

  1. National Natural Science Foundation of China [21175068]
  2. Priority Academic Program Development of Jiangsu Higher Education Institutions
  3. Jiangsu Collaborative Innovation Center of Biomedical Functional Materials

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The pristine graphene can be easily prepared in isopropanol-water mixture with salts as assistant via liquid-phase exfoliation method. The concentration of graphene dispersion reaches as high as 0.565 mg/mL. The graphene film prepared by drop-casting method shows an excellent electrical conductivity (7.095 x 10(4) S/m). Furthermore, an electrochemical biosensor based on the pristine graphene shows high selectivity and sensitivity for the determination of dopamine. The linear detection range for dopamine is 2.5-1500 mu M with detection limit of 1.5 mu M. This method provides a potential process for preparing high-quality graphene ready-to-use in low-boiling point solvent. (C) 2017 Elsevier Inc. All rights reserved.

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