4.2 Article

Temperatures of Primary Crystallization and Density of the KF + AIF3 + LiF + Al2O3 Molten System

Journal

JOURNAL OF CHEMICAL AND ENGINEERING DATA
Volume 63, Issue 8, Pages 3047-3052

Publisher

AMER CHEMICAL SOC
DOI: 10.1021/acs.jced.8b00157

Keywords

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Funding

  1. Scientific Grant Agency of the Ministry of Education of the Slovak Republic
  2. Slovak Academy of Sciences [2/0114/16]
  3. Slovak Research and Development Agency [APVV-15-0479, SK-CN-2015-0014]
  4. Research & Development Operational Programme - ERDF [26240220070]
  5. programme SASPRO (Mobility Programme of the Slovak Academy of Sciences), Marie Curie Actions of the European Union [1119/02/02]

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This work deals with the investigation of the temperatures of primary crystallization and density of the KF + AlF3 + LiF + Al2O3 molten system for three cryolite ratios (CR = 1.3, 1.5 and 1.7). Thermal analysis and the Archimedean method of hydrostatic weighing were used for the determination of studied properties. The dependence of liquidus temperature on composition shows different trends for different CRs, whereas the density increased with increasing content of LiF for all CRs.

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