Journal
JOURNAL OF CHEMICAL AND ENGINEERING DATA
Volume 63, Issue 7, Pages 2438-2450Publisher
AMER CHEMICAL SOC
DOI: 10.1021/acs.jced.7b00996
Keywords
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Funding
- Consejo Nacional de Ciencia and Tecnologia (CONACyT) [CB-2016-285320]
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This work presents experimentally determined densities and viscosities of biodiesel blended with 1-pentanol, 2-pentanol, and 2-methyl-1-butanol between 288.15 and 338.15 K at 0.1 MPa. The densities are measured using a vibrating tube densimeter, and the kinematic viscosities, using a glass capillary viscometer. The measured density and viscosity of the pure components agree with values reported in the literature within average absolute percentage deviations of 0.04 and 0.83%, respectively. The excess molar volumes and viscosity deviations show positive and negative deviations from ideality, respectively. The Redlich-Kister equation is used to represent the composition behavior of the excess molar volumes and viscosity deviations. The experimental kinematic viscosities have a minimum value over a composition range of 50-90% alcohol by weight. The McAllister equation correlates the kinematic viscosity within an average absolute percentage deviation of 1.77%, while the Nava-Rios equation correlates the kinematic viscosity within 0.88%.
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