Journal
JOURNAL OF CATALYSIS
Volume 361, Issue -, Pages 393-397Publisher
ACADEMIC PRESS INC ELSEVIER SCIENCE
DOI: 10.1016/j.jcat.2018.03.007
Keywords
Amidation; C-H bond functionalization; Cobalt catalysis; Ferrocene
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Funding
- National Key R&D Program of China [2016YFA0202900]
- National Basic Research Program of China (973 Program) [2015CB856600]
- NSFC [21332009, 21572250]
- Strategic Priority Research Program of CAS [XDB20000000, QYZDY-SSW-SLH012]
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ortho-Amidation of 2-pyridinyl ferrocenes with 1,4,2-dioxazol-5-ones was achieved via Cp*Co(III)-catalyzed direct C-H bond functionalization reaction. In the presence of Cp*Co(CO)I-2, in combination with AgPF6 and AgOPiv, a wide range of ferrocene-based amidated products were obtained in up to 96% yield under mild reaction conditions. A gram-scale reaction proceeded smoothly with high efficiency. Isoquinoline and pyrimidine are also suitable directing groups in this transformation. (C) 2018 Elsevier Inc. All rights reserved.
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