4.7 Article

Self-calibrating optic thermometer based on dual-emission nanocomposite

Journal

JOURNAL OF ALLOYS AND COMPOUNDS
Volume 730, Issue -, Pages 12-16

Publisher

ELSEVIER SCIENCE SA
DOI: 10.1016/j.jallcom.2017.09.282

Keywords

In2O3; Eu3+; Nanocomposite; Optical thermometer

Funding

  1. National Natural Science Foundation of China [51503036]
  2. Natural Science Foundation of Fujian Province [2015J01632, 2015J05091, 2016J01752, 2017J01676, 2017J01677]
  3. Fujian Province University (Minjiaoke) [23, 54]
  4. Fujian Education Department [JZ160484, JZ160486, JA15534, JA15536]

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A new approach to optical thermometers with high sensitivity was developed herein by using In2O3 quantum dots (QDs) emission as temperature detecting signal and Eu3+ ions emission as reference one. Originated from the diverse thermal quenching behavior between the defect-related emission of In2O3 QDs and 4f-4f transitions of Eu3+ ions, fluorescence intensity ratio of In2O3 to Eu3+ in nanocomposite exhibited excellent temperature sensing property in the range from 303 K to 543 K. The maximum absolute and relative temperature sensitivity can reach as high as 4.43 x 10(-2) K-1 and 0.89% K-1, respectively. We believe that this work exploits an effective pathway for developing other innovative optical thermometers. (C) 2017 Elsevier B.V. All rights reserved.

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