Journal
JOURNAL OF ALLOYS AND COMPOUNDS
Volume 745, Issue -, Pages 135-146Publisher
ELSEVIER SCIENCE SA
DOI: 10.1016/j.jallcom.2018.02.172
Keywords
Solution combustion; CNTs/C/NiMoO4; Electrochemical properties; Asymmetric supercapacitor; Energy density
Categories
Funding
- National Natural Science Foundation of China [51401140]
- Specialized Research Fund for the Doctoral Program of Higher Education of China [20131402110003, 20131402120004]
- Natural Science Foundation for Young Scientists of Shanxi Province, China [2014021018-1]
- Program for the Outstanding Innovative Teams of Higher Learning Institutions of Shanxi (OIT)
- Collaborative Innovation Center for Shanxi Advanced Permanent Magnetic Materials and Technology [2016-06]
Ask authors/readers for more resources
A facile and cost-effective one-time solution combustion method is designed for the synthetic of CNTs/C/NiMoO4 and C/NiMoO4 porous composites at 300 degrees C for 0.5 h in the atmosphere. The characteristics of products are investigated by advanced physical property test and electrochemical analysis. The results reveal that the electrochemical performances of C/NiMoO4 composites are strongly influenced by the molar ratio of oxidizer to fuel and the largest specific capacitance of the optimized sample reaches 859 F g(-1) at 1 A g(-1). Moreover, the capacitance of CNTs/C/NiMoO4 composites has been further enhanced to 1037 F g(-1) at 1 A g(-1), in which added acid-treated CNTs into the precursor mixed solution in the combustion process. Furthermore, an asymmetric supercapacitor CNTs/C/NiMoO4 parallel to activated carbon (AC) is assembled, which the CNTs/C/NiMoO4 used as cathode and AC used as anode. Its energy density of 32.6 Wh kg(-1) at power density of 150.5Wk g(-1) and even retains 18.2 Wh kg(-1) at 8509 Wk g(-1). This asymmetric device exhibits a well cycle stability, which the capacitance retain 96.5% after 1500 cycles. The excellent electrochemical behaviors indicate that CNTs/C/NiMoO4 composites have great potential for application in high capacity energy storage devices. (C) 2018 Elsevier B.V. All rights reserved.
Authors
I am an author on this paper
Click your name to claim this paper and add it to your profile.
Reviews
Recommended
No Data Available