Journal
ARKIVOC
Volume -, Issue -, Pages 1-9Publisher
ARKAT USA INC
DOI: 10.3998/ark.5550190.p008.872
Keywords
Ovothiol; antioxidant; trypanosomatid; histidine
Categories
Funding
- TAMOP [4.2.1.B-09/1/KMR]
- OTKA [T 73804]
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Ovothiol A is a naturally occurring 4-mercaptohistidine derivative, and one of the most potent thiol-containing antioxidants. The synthesis of ovothiol A was elaborated by introducing the thiol group onto protected 3-methyl-L-histidine via halogenation and Ullmann reaction. This enantiopure synthesis of ovothiol A, which uses L-histidine as starting material, requires only five steps, and compared to prior synthesis, is both cost and time effiecent.
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