4.1 Article

One-pot synthesis-assembly-separation of cucurbit[6]uril via SO3H-functionalized ionic liquids

Journal

Publisher

SPRINGER
DOI: 10.1007/s10847-014-0426-2

Keywords

Supramolecular; Cucurbituril; Ionic liquid; Anion; Microwave

Funding

  1. State Key Laboratory of Fine Chemicals
  2. National Natural Science Foundation of China [21003123]
  3. Fundamental Research Funds for the Central Universities

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A novel microwave-assisted route to synthesize cucurbit[n]uril in SO3H-functionalized ionic liquids was reported, which enabled the automatic separation of cucurbit[6]uril through anion assembly. For the first time, the route has realized synthesis-assembly-separation of cucurbit[6]uril in one pot. The reaction yield and separation efficiency can be tuned by choice of anionic groups in ionic liquids.

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