Journal
JOURNAL OF INCLUSION PHENOMENA AND MACROCYCLIC CHEMISTRY
Volume 80, Issue 3-4, Pages 345-351Publisher
SPRINGER
DOI: 10.1007/s10847-014-0411-9
Keywords
Secoisolariciresinol diglucoside; Metal chelation; Mass spectrometry; Semiempirical model
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Funding
- Interreg IVA (South) project [4044 Flax]
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Secoisolariciresinol diglucoside (SDG) is a polyphenolic phytoestrogen which is particularly abundant in flaxseed. As a diphenolic compound, SDG is expected to function as a metal chelating ligand. The affinity of SDG for metal cations was determined using a mass spectrometric approach. Experiments yielded equilibrium constants in aqueous solution for SDG center dot Ca2+, SDG center dot Cu2+, SDG center dot Pb2+, SDG center dot Ni2+, SDG center dot Fe2+ and SDG center dot Ag+ of 20.34, 5.99, 4.26, 2.77, 2.46 and 1.90, respectively. These values are consistent with those determined for plant phenolics. Semiempirical calculations for the SDG metal complexes yield an insight into their likely structures.
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