Journal
INTERNATIONAL JOURNAL OF ELECTROCHEMICAL SCIENCE
Volume 13, Issue 5, Pages 4923-4932Publisher
ESG
DOI: 10.20964/2018.05.12
Keywords
Tramadol; MgO/SWCNTs nanocomposite; 1,3-dipropylimidazolium bromide; Electrochemical sensor
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The electrochemical behavior of tramadol at carbon paste electrode amplified with the 1,3-dipropylimidazolium bromide and MgO/SWCNTs nanocomposite (1,3-DI-Br/MgO/SWCNTs/CPE) has been studied in aqueous solutions. The oxidation of tramadol at the pH range of 6.0-9.0 has been investigated. At the optimum condition of pH 8.0, the tramadol shows an irreversible signal at 0.81 V. The scan rate investigation confirms a diffusion process for the electro-oxidation of tramadol at a surface of 1,3-DI-Br/MgO/SWCNTs/CPE. Square wave voltammetric investigation shows a linear relation between the tramadol current and concentration within the range of 0.05-280 mu M with a detection limit of 8.0 nM. The 1,3-DI-Br/MgO/SWCNTs/CPE has been applied to analyze the tramadol in injection and urine samples.
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