Journal
INTERNATIONAL JOURNAL OF ELECTROCHEMICAL SCIENCE
Volume 13, Issue 2, Pages 2126-2135Publisher
ESG
DOI: 10.20964/2018.02.66
Keywords
PEDOT; Transition metals; Rutin; Electrochemical detection; Sensor
Categories
Funding
- National Natural Science Foundation of China [21665010, 51302117]
- outstanding youth fund of Jiangxi Province [20162BCB23027]
- Natural Science Foundation of Jiangxi Province [20171BAB203015, 20151BAB203018, 2014BBF60002]
- State Key Laboratory of Chemical Biosensing Chemometrics [2015010]
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Herein, poly(3,4-ethylenedioxythiophene) (PEDOT) films doped with transition metals were electrochemically synthesized. Transition metal ions-EDTA (M-EDTA, = Cu2+, Mn2+, Fe3+, CO2+, Ni2+) complexes served as dopants. Rutin as model molecular was utilized to investigate its electrochemical responses at PEDOT/M-EDTA modified electrodes. It was found the PEDOT/Co2+-EDTA exhibited better electrocatalytic activity toward rutin oxidation than other PEDOT/M-EDTA modified electrodes. Thus, PEDOT/Co2+-EDTA film-based electrochemical sensor was used to detect rutin. Low detection limit (1.67 nM), good reproducibility and wide linear range (5 nM-100 mu M) were obtained. The sensor was employed for the determination of rutin in buckwheat tea. These results suggest that PEDOT/Co2+-EDTA could be utilized as a promising sensing platform for rutin detection.
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