Journal
INORGANICA CHIMICA ACTA
Volume 478, Issue -, Pages 195-210Publisher
ELSEVIER SCIENCE SA
DOI: 10.1016/j.ica.2018.04.015
Keywords
Magnetic nanoparticle; Schiff base-palladium(II); Nanomagnetic catalyst; Synthesis and characterization; Suzuki-Miyaura cross-coupling; Reduction of nitroarenes
Categories
Funding
- DST-Nanomission, India [SR/NM/NS-20/2014]
- DST-SERB, India [SERB/F/7013/2015-16]
- Jain University, India
Ask authors/readers for more resources
In the current work, a new stable and powerful magnetic nanoparticle supported Schiff base-palladium (II) (MNPs@SB-Pd) nanomagnetic catalyst was synthesized. The structural feature of the MNPs@SB-Pd nanomagnetic catalyst was properly characterized using a combination of attenuated total reflectance infrared spectroscopy (ATR-IR), ultraviolet-visible spectroscopy (UV-Visible), inductively coupled plasma-atomic emission spectroscopy (ICP-AES), energy-dispersive X-ray spectroscopy (EDS), field-emission scanning electron microscopy (FESEM), transmission electron microscopy (TEM), X-ray powder diffraction (XRD), thermogravimetric analysis (TGA) and Brunauer-Emmett-Teller surface area analysis (BET). The air-and moisture stable prepared MNPs@SB-Pd nanomagnetic catalyst was applied in C-C bond formation through Suzuki-Miyaura cross-coupling reactions and reduction of nitroarenes. Use of green medium, eco-friendly, waste-free, efficient preparation leading to high yield of products, short reaction time and cost effective catalyst are the major benefits of the method presented. In addition, the MNPs@SB-Pd nanomagnetic catalyst was easily separated from the reaction mixture with the help of an external magnetic field and reused for five consecutive cycles in Suzuki-Miyaura cross-coupling and ten consecutive cycles in reduction of nitroarene reactions with no significant loss of catalytic efficiency. (C) 2018 Elsevier B.V. All rights reserved.
Authors
I am an author on this paper
Click your name to claim this paper and add it to your profile.
Reviews
Recommended
No Data Available