Journal
INORGANIC CHEMISTRY COMMUNICATIONS
Volume 91, Issue -, Pages 63-66Publisher
ELSEVIER
DOI: 10.1016/j.inoche.2018.03.002
Keywords
Tris-pyrazolonate hetero-binudear complex; Grafting hybrid material; NIR luminescence; Energy transfer
Categories
Funding
- NNSF [21373160, 51578447]
- Northwest University in P. R. of China [YZZ17127]
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Through copolymerization of MMA (methyl methacrylate) with the vinyl-functionalized and Iris-pyrazolonate hetero-binuclear complex monomer [Zn(L-1)(4-vinyl-Py)Yb(L-2)(3)] (3;H2L1 = N,N'-bis(salicylidene)cyclohexane-1,2-diamine; 4-vinyl-Py = 4-vinyl-pyridine and HL2 = (Z)-3-methyl-1-phenyl-4-(2,2,2-trifluoro-1-hydroxyethylidene)-1H-pyrazol-5(4H)-one), the obtained PMMA-supported grafting hybrid materials Poly (MMA-co-3) exhibit ideal physical properties including the desirable Yb3+-centered MR efficiency (Phi(L)(Yb) up to 1.29%). (C) 2018 Elsevier B.V. All rights reserved.
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