Journal
INORGANIC CHEMISTRY COMMUNICATIONS
Volume 87, Issue -, Pages 20-23Publisher
ELSEVIER SCIENCE BV
DOI: 10.1016/j.inoche.2017.11.014
Keywords
Gadolinium(III); 3D polymer; Ferromagnetic behaviour; Magnetocaloric effect
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Funding
- National Natural Science Foundation of China (NSFC) [21401126, 21371114, 21571123, 21601119, 21471095]
- Scientific and Technological Projects of Science and Technology Department of Henan province [172102210437]
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One three-dimensional Gd(III) coordination polymer with 1,2-phenylenediacetate (PDA(2-)), [Gd-2(PDA)(3)(H2O)(2)].3H(2)O (1), has been successfully synthesized and characterized. Single-crystal X-ray diffraction analysis shows that 1 consists of 1D wave Gd-based chain unit and PDA(2-)linker. Magnetic studies suggest the presence of ferromagnetic Gd-Gd coupling in the 1D chain unit of 1. Meanwhile, 1 has a significant cryogenic magnetocaloric effect with the maximum -Delta S-m of 33.44 at 2K and 7T. (C) 2017 Elsevier B.V. All rights reserved.
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