4.7 Article

Beyond Crystal Engineering: Significant Enhancement of C2H2/CO2 Separation by Constructing Composite Material

Journal

INORGANIC CHEMISTRY
Volume 57, Issue 7, Pages 3679-3682

Publisher

AMER CHEMICAL SOC
DOI: 10.1021/acs.inorgchem.8b00341

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Funding

  1. NSF of China [21661001, 21661002]
  2. Innovation Fund Designated for Graduate Students of Jiangxi Province [YC2017-S275]

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Different from the established crystal engineering method for enhancing gas-separation performance, we demonstrate herein a distinct approach. In contrast to the pristine MOF (metal-organic framework) material, the C2H2/CO2 separation ability for the resultant Ag NPs (nanopartide)@Fe2O3@MOF composite material, estimated from breakthrough calculations, is greatly enhanced by 2 times, and further magnified up to 3 times under visible light irradiation.

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