Journal
INORGANIC CHEMISTRY
Volume 57, Issue 7, Pages 3818-3824Publisher
AMER CHEMICAL SOC
DOI: 10.1021/acs.inorgchem.7b03174
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Funding
- National Natural Science Foundation of China [21501036, 21676066]
- Science Foundation of Heilongjiang Province, People's Republic of China [E2016042]
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Rapid and large-scale synthesis of metal organic frameworks (MOFs) materials is of great significance for their practical applications. For the first time, we have electrochemically synthesized IRMOF-3 at room temperature by applying a voltage to a zinc electrode immersed in electrolyte containing 2-aminoterephthalic acid (NH2-H2BDC). The reaction conditions, including the ratio of solvent (electrolyte), the applied voltage, and different reaction times, were investigated and optimized. The degree of crystallinity and nanomorphology of the synthesized IRMOF-3 can be controlled by changing the reaction importantly, we demonstrated that the electrochemical synthesis strategy can rapidly obtain nanoscale IRMOF-3 with high crystallinity on a gram scale. In addition, in comparison with the product of solvothermal synthesis, the electrochemically synthesized nanoscale IRMOF-3 exhibits improved fluorescent detection ability to 2,4,6-trinitrophenol (TNP) with a detection limit of about 0.1 ppm.
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