Journal
INORGANIC CHEMISTRY
Volume 57, Issue 11, Pages 6710-6715Publisher
AMER CHEMICAL SOC
DOI: 10.1021/acs.inorgchem.8b00907
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Funding
- National Natural Science Foundation of China [21671142]
- Jiangsu Province Natural Science Fund for Distinguished Young Scholars [BK20160006]
- Priority Academic Program Development of Jiangsu Higher Education Institutions (PAPD)
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Reported here is a unique crystalline semiconductor open framework material built from the large-sized supertetrahedral T4 and T5 clusters with the Mn-In-S compositions. The hybrid assembly between T4 and T5 clusters by sharing terminal mu(2)-S2- is for the first time observed among the cluster-based chalcogenide open frameworks. Such threedimensional structure displays non-interpenetrated diamond-type topology with extra-large nonframework volume of 82%. Moreover, ion exchange, CO2 adsorption, as well as photoluminescence properties of the title compound are also investigated.
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