Journal
INORGANIC CHEMISTRY
Volume 57, Issue 3, Pages 903-907Publisher
AMER CHEMICAL SOC
DOI: 10.1021/acs.inorgchem.7b02623
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Funding
- National Natural Science Foundation of China [21422704, 21471107, 21790370, 21790374, 21761132019]
- Science Challenge Project [JCKY2016212A504]
- Young Thousand Talented Program
- China Postdoctoral Science Foundation [2016M591901]
- Priority Academic Program Development of Jiangsu Higher Education Institutions
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The first heterobimetallic uranium(IV)/vanadium(III) phosphite compound, Na2UV2(HPO3)(6) (denoted as UVP), was synthesized via an in situ redox-active hydrothermal reaction. It exhibits superior hydrolytic and antioxidant stability compared to the majority of structures containing low-valent uranium or vanadium, further elucidated by first-principles simulations, and therefore shows potential applications in nuclear waste management.
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