Journal
INORGANIC CHEMISTRY
Volume 57, Issue 4, Pages 1912-1918Publisher
AMER CHEMICAL SOC
DOI: 10.1021/acs.inorgchem.7b02814
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Funding
- National Science Foundation [CHE-1464887]
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(DME)(2)Ln(SeC6F5)(3) (Ln = Nd, Er, Tm) can be isolated in high yield by reductive cleavage of the Se-Se bond in (SeC6F5)(2) with elemental Ln in DME. All three Ln compounds are isostructural, with 8 coordinate Ln bound to four O from DME, three terminally bound Se(C6F5), and a dative bond from an arene fluoride to a fluorine at the ortho position of one selenolate. Emission measurements indicate that these compounds are bright NIR sources.
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