Journal
HIGH PERFORMANCE POLYMERS
Volume 31, Issue 6, Pages 679-685Publisher
SAGE PUBLICATIONS LTD
DOI: 10.1177/0954008318784144
Keywords
Sulfonated polyimide; phosphotungstic acid; vanadium redox flow battery; composite membrane
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A novel sulfonated polyimide (SPI) membrane embedded with the phosphotungstic acid (SPI/PWA membrane) for vanadium redox flow battery (VRB) has been prepared with low capacity loss, low cost, and high energy efficiency (EE); the proportion of PWA in the composite membrane is 15%. The mechanical strength, vanadium ions permeability, and performance of the membrane in the VRB single cell were characterized. Results showed that the SPI/PWA membrane possessed low permeability of vanadium ions, accompanied by higher mechanical strength than the Nafion117 membrane. The VRB single cell with SPI/PWA composite membrane showed 7.6% higher coulombic efficiency, 4.6% higher EE, but lower capacity loss in comparison with the one with Nafion117 membrane at the current density 40 mA cm(-2). The good cell performance, low capacity loss, and high vanadium ions barrier properties of the blend membrane is of significant interest for VRB applications.
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