Journal
RSC ADVANCES
Volume 5, Issue 21, Pages 16405-16413Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c4ra15894f
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Funding
- Swedish Foundation for Strategic Research (SSF) [RMA-110012]
- Swedish Science Council (VR)
- Bo Rydin Foundation
- Swedish Energy Agency
- Carl Trygger Foundation
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Asymmetric, all-organic supercapacitors (containing an aqueous electrolyte), exhibiting a capacitance of 25 F g(-1) (or 2.3 F cm(-2)) at a current density of 20 mA cm(-2) and a maximum cell voltage of 1.6 V, are presented. The devices contain a composite consisting of polypyrrole covered Cladophora cellulose fibres (PPy-cellulose) as the positive electrode while a carbon nanofibre material, obtained by heat treatment of the same PPy-cellulose composite under nitrogen gas flow, serves as the negative electrode. Scanning and transmission electron microscopy combined with X-ray photoelectron spectroscopy data show that the heat treatment gives rise to a porous carbon nanofibre material, topologically almost identical to the original PPy-cellulose composite. The specific gravimetric capacitances of the carbon and the PPycellulose electrodes were found to be 59 and 146 F g(-1), respectively, while the asymmetric supercapacitors exhibited a gravimetric energy density of 33 J g(-1). The latter value is about two times higher than the energy densities obtainable for a symmetric PPy-cellulose device as a result of the larger cell voltage range accessible. The capacitance obtained for the asymmetric devices at a current density of 156 mA cm(-2) was 11 F g(-1) and cycling stability results further indicate that the capacity loss was about 23% during 1000 cycles employing a current density of 20 mA cm(-2). The present results represent a significant step forward towards the realization of all-organic material based supercapacitors with aqueous electrolytes and commercially viable capacitances and energy densities.
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