Journal
GREEN CHEMISTRY
Volume 20, Issue 16, Pages 3761-3771Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c8gc01886c
Keywords
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Funding
- NRF grant [2016R1A2B4010181]
- NRF Basic Research Laboratory Program [2016R1A4A1011451]
- National Research Foundation of Korea [2016R1A2B4010181, 2016R1A4A1011451] Funding Source: Korea Institute of Science & Technology Information (KISTI), National Science & Technology Information Service (NTIS)
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An efficient and straightforward reaction protocol for the conversion of lignin model compounds was developed based on a simple system consisting of a base, oxygen, and a green solvent under mild conditions in the absence of metals. This protocol was successfully applied to the cleavage of both beta-O-4' dimeric and trimeric compounds, and a controlled selective degradation was achieved depending on the bond type. The feasibility of this method to provide aromatic compounds in high yields from lignin by a sequential oxidative dehomologation reaction was clearly demonstrated.
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