Journal
GREEN CHEMISTRY
Volume 20, Issue 5, Pages 964-968Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c7gc03539j
Keywords
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Funding
- Universite de Montpellier
- CNRS
- French Ministry of Higher Education and Research
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Herein is described a mechanochemical one-pot two-step procedure giving access to various NHC (N-heterocyclic carbene) precursors. This original approach enabled the production of the widely used IPr center dot HCl, IMes center dot HCl, Io-Tol center dot HCl and ICy center dot HCl in much better yields than conventional solvent-based procedures, while the environmental impact was drastically reduced.
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