Journal
GREEN CHEMISTRY
Volume 20, Issue 6, Pages 1228-1232Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c7gc03775a
Keywords
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Funding
- Natural Science Foundation of Anhui Province [1708085QB39]
- National Natural Science Foundation of China [21602073]
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A novel catalyst-free addition of thiols to silyl glyoxylates was developed in water, providing an efficient route for the synthesis of -hydroxysilanes. In the activation of silyl glyoxylates, hydrogen bonding is critical to the reaction, and rate acceleration was observed in water. Moreover, the competing Brook rearrangement was significantly suppressed with the assistance of water.
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