Journal
GREEN CHEMISTRY
Volume 20, Issue 9, Pages 1992-1997Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c8gc00441b
Keywords
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Funding
- State Key Laboratory of Pulp and Paper Engineering [2017TS02]
- Science Foundation for Distinguished Young Scholars of Guangdong Province [2014A030306018]
- National Natural Science Foundation of China [21472052]
- Fundamental Research Funds for the Central Universities [2017ZD060]
- 1000-Youth Talents Plan
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Here, we developed a new cobalt nanocatalyst supported on N-SiO2-doped activated carbon (Co/N-SiO2-AC), which exhibits excellent catalytic performance towards the oxidative esterification of (hetero)aryl and alkyl thiols with alcohols. A wide array of sulfinic esters were efficiently afforded in an exclusive chemoselective manner. The developed synthetic method proceeds with the merits of mild reaction conditions, broad substrate scope, operational simplicity, good functional group tolerance, earth-abundant and reusable cobalt catalysts, the utilization of renewable alcohols as the coupling partners and molecular O-2 as the sole oxidant, which offers a practical method for sustainable synthesis of sulfinic esters.
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