Journal
GREEN CHEMISTRY
Volume 20, Issue 1, Pages 130-135Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c7gc02991h
Keywords
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Funding
- Novartis
- NSF (SusChEM) [1566212]
- U.S. Department of Energy (DOE), Office of Basic Energy Sciences, Division of Chemical Sciences, Biosciences and Geosciences [DE-AC02-06CH11357]
- U.S. Department of Energy, Office of Science, and Office of Basic Energy Sciences [DE-AC02-06CH11357]
- Department of Energy
- MRCAT member institutions
- Direct For Mathematical & Physical Scien [1566212] Funding Source: National Science Foundation
- Division Of Chemistry [1566212] Funding Source: National Science Foundation
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A remarkable synergistic effect has been uncovered between ppm levels of Pd and Ni embedded within iron nanoparticles that leads to mild and selective catalytic reductions of nitro-containing aromatics and heteroaromatics in water at room temperature. NaBH4 serves as the source of inexpensive hydride. Broad substrate scope is documented, along with several other features including: low catalyst loading, low residual metal in the products, and recycling of the catalyst and reaction medium, highlight the green nature of this new technology.
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