Journal
GREEN CHEMISTRY
Volume 20, Issue 7, Pages 1467-1471Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c8gc00424b
Keywords
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Funding
- Russian Science Foundation (RSF) [14-23-00231, 17-73-10462]
- RUDN University Program 5-100
- Program of fundamental research for state academies (Engelhardt Institute of Molecular Biology, Russian Academy of Sciences) [01201363818, 01201363817]
- Russian Science Foundation [17-23-00015, 17-73-10462] Funding Source: Russian Science Foundation
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A highly efficient preparative method for the synthesis of siloxanols based on aerobic Co(OAc)(2) or Cu(OAc)(2)/NHPI-catalyzed oxidation of hydride siloxanes using green, commercially available, simple inexpensive reagents and mild reaction conditions has been proposed. This is a general reaction for the synthesis of mono-, oligo- and polymeric siloxanols with various structures (linear, branched and cyclic).
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