Journal
GREEN CHEMISTRY
Volume 20, Issue 8, Pages 1754-1759Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/C8GC00008E
Keywords
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Funding
- Austrian Science Fund (FWF) [I 1637-N19, P 26863-N19]
- Austrian BMWFJ
- BMVIT
- SFG
- Standortagentur Tirol
- ZIT through the Austrian FFG-COMET-Funding Program
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The utilization of gaseous carbon dioxide instead of bicarbonate would greatly facilitate process development for enzyme catalyzed carboxylations on a large scale. As a proof-of-concept, 1,3-di-hydroxybenzene (resorcinol) was carboxylated in the ortho-position using pressurized CO2 (similar to 30-40 bar) catalyzed by ortho-benzoic acid decarboxylases with up to 68% conversion. Optimization studies revealed tight pH-control and enzyme stability as the most important determinants.
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