Journal
RSC ADVANCES
Volume 5, Issue 27, Pages 21297-21300Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c5ra01826a
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Funding
- Japanese government [26288045]
- Grants-in-Aid for Scientific Research [26288045, 14J10059] Funding Source: KAKEN
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A simple generation method of carbon radicals via 1e-oxidation of organotrifluoroborates and carboxylic acids by the action of an organophotoredox catalyst, 9-mesityl-10-methylacridinium perchlorate ([Acr(+)-Mes]ClO4), has been developed. This organophotocatalytic protocol is amenable to radical C-C bond formation with electron-deficient olefins.
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