Journal
FUEL
Volume 226, Issue -, Pages 417-422Publisher
ELSEVIER SCI LTD
DOI: 10.1016/j.fuel.2018.03.193
Keywords
5-Hydroxymethylfurfural; Glucose; Phosphotungstic acid; Silica gel
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Funding
- NSFC - China [21503098, 21603089]
- TAPP
- PAPD
- Jiangsu Province Science Foundation for Youths [BK20160209]
- Natural Science Foundation of the Higher Education Institutions of Jiangsu Province [15KJB150005, 15KJD530002, 16KJB150014]
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Conversion of carbohydrates into 5-hydroxymethylfurfural (HMF) is a valuable reaction for biomass efficient utilization. The silica-supported phosphotungstic acid (PTA) heterogeneous catalyst (SiO2-ATS-PTA) was prepared and characterized by XRD, FT-IR, pyridine-FTIR and SEM. The SiO2-ATS-PTA was used to catalyze the conversion of glucose, and it afforded 78.31% yield of HMF at 160 degrees C for 140 min. The SiO2-ATS-PTA could be reused for five runs without significant loss of catalytic activity. Furfural was the main byproduct. A kinetic analysis was carried out and the values of the activation energy and the pre-exponential factor for the reaction were 30.25 kJ mol(-1) and 1.08x10(7) min(-1), respectively.
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