Journal
FLUID PHASE EQUILIBRIA
Volume 459, Issue -, Pages 219-229Publisher
ELSEVIER SCIENCE BV
DOI: 10.1016/j.fluid.2017.07.020
Keywords
High pressure; Polymorphism; Two-component system
Funding
- Spanish Ministry of Economy and Competitivity (MEC) [FIS2014-54734P]
- Catalan government (AGAUR) [2014SGR-581]
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The temperature-composition phase diagram of the two-component system 1-Br-adamantane and 1-C1adamantane has been determined by means of thermal analysis techniques and X-ray powder diffraction from the low-temperature phase to the liquid state. The crossed isopolymorphism formalism has been applied to the two-component system to infer the normal pressure properties of the orthorhombic metastable phase of 1-C1-adamantane at normal pressure. The experimental pressure-temperature phase diagrams for the involved compounds are related to the two-phase equilibria determined at normal pressure and inferences about the monotropic behavior of the aforementioned orthorhombic phase are discussed. (C) 2017 Elsevier B.V. All rights reserved.
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