Journal
EXPRESS POLYMER LETTERS
Volume 12, Issue 9, Pages 844-854Publisher
BUDAPEST UNIV TECHNOL & ECON
DOI: 10.3144/expresspolymlett.2018.72
Keywords
nanocomposites; cellulose nanofibers; pineapple leaves; transparent
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Funding
- Ministry of Science and Technology of Taiwan [MOST 104-2221-E-324-024-]
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In this study, cellulose nanofibers (CNFs) were derived from waste pineapple leaves with the aim of developing a nanocomposite with high impact strength and transparency. First, CNFs were prepared using an acid-base treatment and 2,2,6,6-tetramethylpiperidin-1-oxyl radical (TEMPO)-mediated oxidation, and then, the surface was modified with polymerized methyl methacrylate (MMA) using an eco-friendly method in an aqueous system. The MMA-modified CNF had an increased contact angle from 12.02 to 57.45 degrees, and the surface hydrophobicity improved the interfacial compatibility between the CNF and polymethyl methacrylate (PMMA) matrix. At 1-3 wt% of the modified CNF, the impact strength of the nanocomposites was significantly improved by 2.7-22.9%. Moreover, this eco-friendly modification allowed CNFs to disperse homogeneously in the nanocomposite for excellent light transmittance. In conclusion, this eco-friendly modification can replace conventional solvent-based modification, allowing modified CNF to effectively reinforce the PMMA nanocomposite.
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